Transport and Deposition of Carbon Nanoparticles in Saturated Porous Media
نویسندگان
چکیده
Carbon nanoparticles (CNPs) are becoming promising candidates for oil/gas applications due to their biocompatibility and size-dependent optical and electronic properties. Their applications, however, are always associated with the flow of nanoparticles inside a reservoir, i.e., a porous medium, where insufficient studies have been conducted. In this work, we synthesized CNPs with two different size categories in 200 nm carbon balls (CNP-200) and 5 nm carbon dots (CNP-5), via a hydrothermal carbonation process. Comprehensive experiments in packed glass bead columns, as well as mathematical simulations, were conducted to understand the transport and deposition of CNPs under various ionic strength, particle sizes and concentration conditions. Our results show that the retention of CNP-200 is highly sensitive to the salinity and particle concentrations, while both of them are unaffected in the transport of small CNP-5. Supplemented with Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, the clean bed filtration theory with blocking effect can successfully fit the experimental breakthrough curves of CNP-200. However, the high breakthrough ability for CNP-5 regardless of ionic strength change is in conflict with the energy interactions predicted by traditional DLVO theory.
منابع مشابه
The influence of biofilms on the mobility of bare and capped zinc oxide nanoparticles in saturated sand and glass beads.
Biofilms are a common constituent of the subsurface and are known to influence contaminant transport; however only a few studies to date have addressed microbial controls on nanoparticle mobility in porous media. The impact of a 3-day Pantoea agglomerans biofilm on the mobility of zinc oxide (ZnO) nanoparticles was studied in column experiments containing sand and glass beads at near-neutral pH...
متن کاملThree-dimensional analytical models for time-dependent coefficients through uniform and varying plane input source in semi-infinite adsorbing porous media.
In the present study, analytical solutions are developed for three-dimensional advection-dispersion equation (ADE) in semi-infinite adsorbing saturated homogeneous porous medium with time dependent dispersion coefficient. It means porosity of the medium is filled with single fluid(water). Dispersion coefficient is considered proportional to seepage velocity while adsorption coefficient inversel...
متن کاملMulti-step Electrophoretic Deposition of α-Al2O3 Nanoparticles on Carbon Substrate (TECHNICAL NOTE)
in the present study, electrophoretic deposition (EPD) was used to obtain dense and crack-free layers of Al2O3 on carbon substrate. Microstructural study of the obtained layers by scanning electron (SEM) and optical microscopy (OM) approved that crack-free layers can be obtained by EPD technique. According to obtained results, isopropanol is a suitable media to obtian compact layers which is at...
متن کاملArticleTransport and deposition of carbon nanoparticles in saturated porous mediaZhongliang Hu 1
Carbon nanoparticles (CNPs) are becoming promising candidates for oil/gas applications due to their biocompatibility and size-dependent optical and electronic properties. Their applications, however, are always associated with the flow of nanoparticles inside a reservoir, i.e., a porous medium, where insufficient studies have been conducted. In this work, we synthesized CNPs with two different ...
متن کاملTransport of cerium oxide nanoparticles in saturated silica media: influences of operational parameters and aqueous chemical conditions
This paper aimed to investigate the influences of operational parameters and aqueous chemical conditions on transport behaviors of cerium oxides nanoparticles (CeO2-NPs) in saturated silica media. Results indicated that increasing rates of attachment efficiency (α) were related with cationic types, and critical deposition concentration (CDC) for divalent cation (Ca2+ and Mg2+) were more than 31...
متن کامل